I noticed this last night, but apparently I wasn’t the only one as Robert Gale over at A Welsh View and Digg also agree that this is one amazing picture of the shuttle launch. The comments on Digg also point out a few other pictures from this and another launch that are similar, as well as pinpoint (by Google Maps) where the pic was taken.
Of course NASA has more, including some in high resolution. Something about a rocket at night makes for some great pictures.