Just from the perspective, it must be 34th and 8th Ave.
Not sure why I even tried taking a picture from this angle, the buildings were almost black in this shot, but thanks to shooting in RAW I was able to post-edit and it all looks much better sans the uncomfortable angle.
That black building to the right is 1 Penn Plaza. I had a training session for a few days in an office on one of the upper floors. AMAZING view of all lower Manhattan. That office was just a regional office and rarely occupied. Such a waste.